Well, adding it via the hose through the PCV valve will add it to the crankcase, not directly into the intake and cylinders.....You are looking at two different cleaning approaches here.
For what its worth, I took the challenge and did mine today, through the intake. I pulled the hose off he shows, used my own length of hose and a small funnel and plugged it onto the intake. I poured it n slowly, then shut off the engine and waited about 10 minutes. On restart, it chugged a little and I got a CEL. Ran it about ten minutes and boy, is there alot of smoke. Took the trusty vag-com out, reset the codes, which were all for misfires, and all has been well for the 100 miles I did tonight. It does seem a little more responsive...time will tell.
Next week I am getting the oil changed and I will do a treatment in the oil right before that.
Back to your original question, I am not sure if adding it to the hose that connects to the PCV valve will clean it out well or not.