.... I was just wondering as to the learning curve going from a gas powered engine to a diesel.
I'll write this basic stuff, until the V10 guys chime in with some model specifics.
Having owned VW diesel products for about a decade, I'd say there's nothing really much more to it, when comparing with gassers of before as far as DIY goes. Well for starters, train yourself, especially where you live, to drain the diesel filter of any water. Special tap spout for that. Be slightly more vigilant with what kind of fuel you put into the tank, and when the forecast is for REALLY COLD temps, add a bottle of the PowerService, or Stanadyne(sold at VW dealers here in Canada, perhaps there too), not so much that the engine won't start without it, but it will be smoother and easier to your ears on initial start, and probably better for it too, less wear and tear on the mounts, etc, imho. Obviously, you will never have to worry about plugs, coils, and all that electrical wiring ever ever again, so that is one less thing to worry about big time. Then again, you will now have glow plugs instead, which although they do last a long time, VW has been having some issues with their ceramic glow plugs(tips breaking off and falling into the engine

) and issued a recall on many of its models(recall was suspended due to bad ECU flash reprogramming, not allowing for very good cold temperature starts last I heard

), although the recall in official VW literature, was based on emissions alone.
Wear glove(s) at some self serve diesel centers, or at least a cotton rag in your trunk, as your hand will stink, and/or mess up your fine leathered steering wheel. But all in all, going back to maintenance on a diesel vehicle, from a gasser, nothing more tool wise that you will need. Generally speaking.
Oh yes. One thing came to mind. When you change your diesel filter. Do some reading up on the right procedure for your particular model (V10 in your case), as air bubbles do have a tendency to get in after disconnecting the old, and installing the new filter. Restarting can be a real bitch at times.