I've got a North American 2014 with 100 liter tank. FWIW, the Touareg has by far the most hyper-accurate fuel gave I've ever seen on a car. When it says full, it is full. When it says 3/4, it is 3/4. When it says half, it is half, etc. I tested it by filling the tank when the gauge was reading different amounts, and it was spot on every single time. Assuming the 85 liter is similar, you can just top off the tank when it reads exactly 3/4 or 1/2, and extrapolate that to the full tank size.
I suspect the "gauge" is actually just a number calculated by subtracting fuel based on how much is pumped through the fuel injectors. And the float is only used to reset the level when you add fuel to the tank (if you add a very small amount, like 1 gallon / 4 liters, it won't register that any fuel has been added, and the gauge won't move). So the accuracy may be diminished if you repeatedly don't fill up the tank to full.